Imikhiqizo

I-1,3,6-Hexanetricarbonitrile iyingxenye ebalulekile yezinhlelo zokusebenza eziningi zezimboni.Isibonelo, iqembu le-tricarboxy elingasetshenziswa njenge-detergent lingatholakala nge-hydrolysis.I-hydrogenation ehambisanayo ye-trinitrile ikhiqiza i-1,3,6-triaminohexane, engase ifakwe i-phosgenated ngesinyathelo esengeziwe ukuze ikhiqize i-1,3,6-triisocyanatohexane.Le nhlanganisela isetshenziswa njengesakhiwo esibalulekile esiyisisekelo kukhemikhali ye-polyurethane (PU), isibonelo ekulungiseleleni izinamatheliso ze-polyurethane noma i-polyurethane coatings.I-1,3,6-Hexanetrinitrile iyisengezo esibalulekile se-electrolyte, futhi ukwakheka kwe-electrolyte kunciphisa ukusetshenziswa kwezinto ezinhle nezimbi ze-electrode ku-voltage ephezulu, i-organic carbonates yendabuko (njenge-chain carbonate DEC, DMC, EMC kanye ne-cyclic carbonate PC, EC, njll.) izobola ngaphansi kwamandla kagesi aphezulu [2,3].Ngakho-ke, ukuthuthukiswa kwezinyibilikisi ezintsha ze-organic ezinamafasitela abanzi we-electrochemical, ukuncibilika okuphezulu kusawoti we-lithium, kanye nobuthi obuphansi sekungenye yezinto ezigxilwe ekuthuthukisweni kwama-electrolyte aphezulu.Izinyibilikisi ze-nitrile organic ngokuvamile zinezakhiwo ezinhle kakhulu njengefasitela elibanzi le-electrochemical, ukuzinza okuphezulu kwe-anode, i-viscosity ephansi kanye nephuzu lokubilisa eliphezulu [4].Ngaphezu kwalokho, imikhiqizo ebolayo yezinyibilikisi eziphilayo eziqukethe amaqembu e-nitrile ngokuvamile ama-carboxylate, ama-aldehyde noma izinyibilikisi zemvelo ezihambisanayo.I-Amine, awekho ama-CN- ion anobuthi kakhulu azokhiqizwa ngesikhathi sokusetshenziswa [5-7].Izinyibilikisi ze-nitrile zinamafasitela abanzi kagesi kagesi futhi zithembisa izincibilikisi ezintsha zemvelo.Kodwa-ke, ngokombono wokusebenza kwe-electrochemical yamabhethri e-lithium-ion, izinyibilikisi ze-nitrile zisenezinkinga zokuhambisana nama-electrode angalungile.Ukwakha uhlelo lokuhlanganisa nge-carbonate solvents noma ukwengeza usawoti oxubile I-LiBOB ingathuthukisa le nkinga ngezinga elithile.