I-Lithium triflate CAS: 33454-82-9
Inombolo Yekhathalogi | XD93596 |
Igama Lomkhiqizo | I-Lithium triflate |
I-CAS | 33454-82-9 |
Ifomu le-Molecularla | I-CF3LiO3S |
Isisindo samangqamuzana | 156.01 |
Imininingwane Yesitoreji | I-ambient |
Ukucaciswa Komkhiqizo
Ukubukeka | Impushana emhlophe |
U-Asay | 99% iminithi |
I-Lithium triflate (LiOTf) iyinhlanganisela yamakhemikhali eyakhiwe ngama-lithium cations kanye nama-anions e-trifluoromethanesulfonate (OTf).Kuyikristalu emhlophe eqinile encibilika kakhulu kuzincibilikisi ze-polar ezifana namanzi notshwala.I-Lithium triflate inezinhlobonhlobo zokusetshenziswa ezinhlelweni ezehlukene zesayensi nezimboni.Okunye okubalulekile kokusetshenziswa kwe-lithium triflate kunjenge-catalyst kanye ne-co-catalyst ku-organic synthesis.Inekhono eliyingqayizivele lokwenza kusebenze futhi likhuthaze ukusabela okuhlukahlukene, okuhlanganisa ukwakheka kwebhondi ye-carbon-carbon, i-oxidation, nokusabela okuhlela kabusha.I-acidity ephezulu ye-Lewis iyenza ibe yisisusa esisebenzayo soguquko olubanzi.Ngaphezu kwalokho, i-lithium triflate ingasetshenziswa njenge-co-catalyst ihlanganiswe namanye ama-catalyst ensimbi yoguquko ukuthuthukisa ukusebenza kabusha nokukhetha kwawo.Lokhu kwenza i-lithium triflate ibe i-reagent ebalulekile ekuhlanganiseni kwemithi, imikhiqizo yemvelo, namakhemikhali amahle.I-Lithium triflate iphinde isetshenziswe njenge-electrolyte kumabhethri e-lithium-ion.Isebenza njengendlela yokuqhuba phakathi kwe-cathode ne-anode, evumela ukugeleza kwe-lithium ion ngesikhathi sokushaja nokukhipha imijikelezo.I-conductivity ephezulu kagesi, i-viscosity ephansi, nokuzinza okuhle kokushisa kuyenza ibe inketho ekahle yamabhethri anamandla amakhulu kanye namandla aphezulu.I-Lithium triflate yenza ukusebenza kahle nokuthembekile kwamabhethri e-lithium-ion, asetshenziswa kakhulu ezintweni zikagesi eziphathwayo, ezimotweni zikagesi, nokugcinwa kwamandla avuselelekayo.Okunye ukusetshenziswa okubalulekile kwe-lithium triflate kusesayensi ye-polymer.Isetshenziswa njenge-co-catalyst noma i-initiator ku-polymerization yama-monomer ahlukahlukene, njenge-ethylene, i-propylene, ne-Cyclic Olefin Copolymers (COCs).I-Lithium triflate isiza ukulawula isisindo samangqamuzana, i-stereochemistry, kanye ne-microstructure yama-polymers avelayo.Iphinde inikeze ukulawula okuthuthukisiwe kokusabela kwe-polymerization, okuholela ekuvuneni okuphezulu kanye nezakhiwo ezithuthukisiwe emikhiqizweni yokugcina ye-polymer.Ngaphezu kwalokho, i-lithium triflate ithola izinhlelo zokusebenza kuma-supercapacitors, lapho isebenza njenge-electrolyte ukuze kube lula ukugcinwa nokukhululwa okusheshayo kwamandla kagesi.I-ionic conductivity yayo ephezulu kanye nokuzinza okuhle ngaphansi kwezimo zamandla kagesi aphezulu kuyenza ifanelekele ukuthuthukisa ukusebenza kwamadivayisi e-supercapacitor.Kubalulekile ukusho ukuthi i-lithium triflate iyinhlanganisela esebenza kakhulu futhi kufanele iphathwe ngokucophelela.Izinyathelo zokuphepha, ezihlanganisa ukusetshenziswa kwezinto ezifanele zokuvikela kanye nokuhambisana nezinqubo zokuphatha, kufanele zilandelwe.Kafushane, i-lithium triflate iyinhlanganisela ehlukahlukene enezinhlelo zokusebenza ezihlukahlukene.Isetshenziswa kabanzi njenge-catalyst ku-organic synthesis, i-electrolyte kumabhethri e-lithium-ion, i-co-catalyst ekuphenduleni kwe-polymerization, kanye ne-electrolyte kuma-supercapacitors.Izakhiwo ezihlukile ze-Lithium triflate ziyenza i-reagent ebalulekile ekuthuthukiseni izinkambu ezihlukahlukene zesayensi nezimboni.