Imikhiqizo

I-spectroscopia exubene ngamagagasi amane ethuthukisiwe kathathu isetshenziswa ukuze kubhekwe ukudluliswa kokuhambisana kokudlidliza phakathi kwezindlela zokwelula ze-CO-asymmetric kanye ne-symmetric ye-rhodium(I) dicarbonyl acetylacetonate (RDC).Ukudlulisa ukuhambisana kuwushintsho olungakhiqizi imisebe ye-superposition ehambisanayo yezifunda ze-quantum ukuya endaweni engaphezulu ehambisanayo ehlukile ngenxa yokuhlangana kwamamodi okudlidliza ngokugeza.Womathathu ama-excitation pulses ahambisana nokuhlangana kwe-quantum eyodwa, kodwa ukudlulisa ukuhambisana kuphumela ekuhlanganeni okusha okunamaza ahlukene.I-frequency entsha yokuphumayo ibonwa nge-monochromator eyixazulula kusukela ekuphakameni okunamandla kufrikhwensi yasekuqaleni yenjabulo.Le ndlela yobuciko ixazulula izindlela ezihlanganisa ukudluliswa kokuhambisana, ibandlulula izici ze-spectral ezidalwe kuphela ukuguqulwa kwemisebe, futhi ixazulula okwesikhashana ukuguquguquka okudalwe ukuphazamiseka phakathi kwezindlela zokudlulisa ukuhambisana okuhlukile.Ithiyori ye-Redfield ibambezela ukuguquguquka kwesikhashana emkhawulweni wokuxhamazela, kodwa futhi kuyacaca ukuthi ukudlulisa ukuhambisana kwephula ukuqagela okungokwezwe okusetshenziswa emibonweni eminingi ye-Redfield.Esikhundleni salokho, idinga imiphumela engeyona ye-Markovian nenkumbulo yokugeza.I-RDC ingase inikeze imodeli elula yokuthuthukiswa kwemibono ehlanganisa le miphumela.